
Milica Đukić
Abstract: Corrosive Sulphur - Recurring phenomenon impacting power transformer reliability
Metals corrosion in power transformers and its relation to sulphur contamination was recognized as a problem affecting liquid-filled power transformers for more than two decades. At the beginning it was recognized as copper corrosion which was dealt within the power sector industry and as of today can be considered as well mitigated. Over the last decade, cases of reported failures and evidences of silver corrosion upon inspection of power transformers were also reported. Phenomenon of silver corrosion has drawn much attention in recent five years, owing to the occurrence of corrosive sulphur in modern insulating liquids based on synthetic esters which does not contain sulphur. Again, for third time, CIGRE launched investigation related to corrosive sulphur within SC A2.02 task force in April 2024 to work for one year and observe the extent of the problem and recommend whether more work is needed on the subject. In October 2025 new CIGRE Working group JWG D1/A2 84 was established with the task to study and provide recommendations how to solve silver corrosion problem which is affecting on load tap changers and bushings, although in previous decades two CIGRE WGs dealt with problem of copper corrosion risk assessment and long-term mitigation. CIGRE JWG D1/A2 84 will work for another three years to elaborate on silver corrosion testing, risk assessment and mitigation of ester based insulating liquids, as well as mineral insulating oils, since new reports of silver corrosion in mineral oils and related failures have been reported, including recommendations for mitigation techniques and remedial solutions. Old fashioned corrosion in mineral oils is related in majority of the cases to the presence of disulphides, including DBDS. Phenomenon of insulating liquids contamination with elemental sulphur is in majority related to ester based insulating liquids. Silver sulphide deposition in synthetic ester was found to be governed by low activation energy and faster reaction rate than in mineral oils, as determined in kinetic study based on laboratory experiments. Obviously, the common understanding of the phenomenon, sources of corrosive sulphur and contamination routes including materials compatibility were in the last decades not mature and application solutions in the industry were undermined in standard requirements and to some extent failed to provide best practices. New CIGRE JWG is expected to cross this gap and provide recommendations and guidelines for future standards. This paper attempts to provide better understanding of the phenomenon and sources of reactive sulphur species and influential factors to define risk assessment guidelines driven from the corrosion reaction rates. On the other side, this paper provides innovative sustainable solutions for mitigation of corrosive ester based insulating liquids with positive environmental impact, with the goal to provide full remedial solutions for complete removal of corrosion and restoration of power transformer condition.
Keywords: corrosive sulphur, silver, copper, elemental sulphur, power transformer, On load tap changer
Abstract: Socially and Environmentally harmonized HYDRopower Operations - SE-HYDRO
Hydropower is still the linchpin of the European renewable energy sector, supplying virtually one third of renewable electricity and essential flexibility services. But its future is ever more threatened by environmental degradation, social opposition, and global competition. SE-HYDRO tackles this twin challenge through the development and validation of environmentally and socially inclusive solutions that increase hydropower flexibility without loss of biodiversity or societal confidence. The project pioneers an integrated framework that brings together societal readiness methodologies, environment and hydrological screening tools, AI-based energy management schemes, and cutting-edge turbine utilization approaches, all tested through digital copies of four prototype European hydropower plant sites in Greece, France, Portugal, and Serbia. These four pilots that cover run-of-river, reservoir, cascades, as well as intake-tunnel small plant technologies offer varied testbeds for eco-flexible operation, biodiversity-integrated management, and stakeholder participation. Through co-development with operators, policymakers, local populations, and NGOs, SE-HYDRO instils societal legitimization and speeds up uptake. Its nine Key Exploitable Results offer practical pathways—from new business models to biodiversity-inclusive water management approaches to a European replication and export roadmap. Combined, they underpin Europe’s technological excellence and competitiveness, while instilling hydropower in the wider transition to climate resilience, ecosystem restoration, and societal readiness. SE-HYDRO also addresses one of the most pressing barriers facing the hydropower sector today: the lack of harmonized approaches for balancing energy generation with ecological preservation and community acceptance. By integrating interdisciplinary expertise from engineering, environmental sciences, digital technologies, economics, and social sciences, the project creates a holistic innovation ecosystem capable of supporting the long-term sustainability of hydropower across Europe. The consortium combines leading research organizations, industrial partners, hydropower operators, and public stakeholders to ensure that all developed solutions are technically robust, socially acceptable, and economically feasible. A central aspect of the project is the use of digital twins and predictive analytics that allow operators to evaluate multiple operational scenarios in real time while considering hydrological variability, climate-related risks, energy market demands, and biodiversity constraints. This approach improves decision-making capacity and supports adaptive management strategies that can respond to increasingly uncertain environmental and economic conditions. The project additionally explores methods for reducing turbine-related fish mortality, improving sediment management, and optimizing water use efficiency without compromising electricity production or grid stability. SE-HYDRO contributes directly to major European policy objectives, including the European Green Deal, the Renewable Energy Directive, the EU Biodiversity Strategy, and the Climate Adaptation Strategy. By strengthening the compatibility between renewable energy deployment and ecosystem protection, the project supports a just and resilient energy transition that benefits both people and nature. The knowledge generated throughout the project will be disseminated through policy recommendations, technical guidelines, training activities, and open stakeholder engagement platforms, ensuring broad accessibility and long-term impact beyond the project duration. Ultimately, SE-HYDRO aims to redefine the role of hydropower in Europe by demonstrating that renewable energy systems can become more flexible, efficient, and climate resilient while simultaneously enhancing environmental stewardship and societal trust. In doing so, the project lays the foundation for a new generation of hydropower operations that are not only technologically advanced, but also environmentally responsible and socially inclusive. The project will furthermore strengthen European industrial leadership by supporting market-ready innovations with high replication potential across different geographical and regulatory contexts. SE-HYDRO results are expected to contribute to improved investment confidence, enhanced public engagement practices, and stronger cross-border cooperation in sustainable hydropower operations. By fostering knowledge exchange between pilot regions, the project encourages the transfer of operational models and accelerates the uptake of harmonized hydropower technologies across Europe. In doing so, SE-HYDRO lays strong foundations for a new generation of sustainable hydropower facilities within Europe’s future development.
Keywords: Eco-flexible hydropower, Biodiversity protection, AI-driven dispatch, Societal readiness, Water-energy-ecosystem nexus, Energy digitalisation, Renewable energy
Biography of the presenter
Milica Đukić is a researcher and PhD candidate at the Faculty of Technology and Metallurgy, University of Belgrade, specializing in Chemical Engineering. Her research focuses on insulating fluids for power transformers, with particular emphasis on synthetic esters, corrosive sulfur phenomena, and silver corrosion. She successfully defended her Master’s thesis entitled “Application of the Circular Economy concept and LCA analysis of dehalogenation technology of PCB contaminated transformers”, which laid the groundwork for her expertise in environmental impact assessment. Her doctoral work integrates fundamental studies and practical power system applications. She is the author and co-author of several scientific papers published in international journals. In the IEEE Transactions on Dielectrics and Electrical Insulation, she published the paper “Kinetic Study of Silver Corrosion in Power Transformers Induced by Elemental Sulfur in Synthetic Ester and Comparison with Mineral Oil”, which addresses the critical kinetics of silver corrosion. Furthermore, she is an active member of the international working group CIGRE JWG A2/C3.70 LCA End of Life, contributing to global discussions on sustainable transformer management. Throughout her academic career, Milica has received several prestigious recognitions, including a Special Award from the Serbian Chemical Society, the “Panta Tutundžić” Awards and the “Dositej” Awards.

